ETHYLENE DICHLORIDE | CAMEO Chemicals (2024)

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ETHYLENE DICHLORIDE | CAMEO Chemicals (1)ETHYLENE DICHLORIDE | CAMEO Chemicals (2)

ChemicalIdentifiers | Hazards | ResponseRecommendations |PhysicalProperties |RegulatoryInformation | AlternateChemicalNames

Chemical Identifiers

What is this information?

The Chemical Identifier fields include common identification numbers, theNFPA diamond U.S. Department of Transportation hazard labels, and a general description of the chemical. The information in CAMEO Chemicals comes from a variety of data sources.

CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 107-06-2 ETHYLENE DICHLORIDE | CAMEO Chemicals (3)
  • 1184
  • Flammable Liquid
  • Poison
  • ETHYLENE DICHLORIDE | CAMEO Chemicals (4) EDC
NIOSH Pocket Guide International Chem Safety Card
Ethylene dichlorideETHYLENE DICHLORIDE | CAMEO Chemicals (5)

NFPA 704

Diamond Hazard Value Description
3
20
ETHYLENE DICHLORIDE | CAMEO Chemicals (7) Health 2 Can cause temporary incapacitation or residual injury.
ETHYLENE DICHLORIDE | CAMEO Chemicals (8) Flammability 3 Can be ignited under almost all ambient temperature conditions.
ETHYLENE DICHLORIDE | CAMEO Chemicals (9) Instability 0 Normally stable, even under fire conditions.
ETHYLENE DICHLORIDE | CAMEO Chemicals (10) Special

(NFPA, 2010)

General Description

A clear colorless liquid with a chloroform-like odor. Flash point 56°F. Denser than water and insoluble in water. Vapors are heavier than air. Density 10.4 lb / gal.

Hazards

What is this information?

The Hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. The information in CAMEO Chemicals comes from a variety of data sources.

Reactivity Alerts

  • Highly Flammable

Air & Water Reactions

Highly flammable. Slightly water soluble.

Fire Hazard

Special Hazards of Combustion Products: Toxic and irritating gases (hydrogen chloride, phosgene) are generated.

Behavior in Fire: Vapor is heavier than air and may travel considerable distance to a source of ignition and flash back. (USCG, 1999)

Health Hazard

Inhalation of vapors causes nausea, drunkenness, depression. Contact of liquid with eyes may produce corneal injury. Prolonged contact with skin may cause a burn. (USCG, 1999)

Reactivity Profile

Liquid ammonia and ETHYLENE DICHLORIDE can cause an explosion when mixed, NFPA 491M, 1991. A tank of dimethyl amino propyl amine exploded violently when it reacted with wet ethylene dichloride which had been the tank's previous contents [Doyle 1973]. Halogenated aliphatic compounds, such as ethylene dichloride, are moderately or very reactive. Halogenated organics generally become less reactive as more of their hydrogen atoms are replaced with halogen atoms. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, epoxides, aluminum

Belongs to the Following Reactive Group(s)

  • Halogenated Organic Compounds

Potentially Incompatible Absorbents

No information available.

Response Recommendations

What is this information?

The Response Recommendation fields include isolation and evacuation distances, as well as recommendations for firefighting, non-fire response, protective clothing, and first aid. The information in CAMEO Chemicals comes from a variety of data sources.

Isolation and Evacuation

Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 50 meters (150 feet) in all directions.

SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)

Firefighting

Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:

CAUTION: The majority of these products have a very low flash point. Use of water spray when fighting fire may be inefficient. CAUTION: Methanol (UN1230) will burn with an invisible flame. Use an alternate method of detection (thermal camera, broom handle, etc.).

SMALL FIRE: Dry chemical, CO2, water spray or alcohol-resistant foam.

LARGE FIRE: Water spray, fog or alcohol-resistant foam. If it can be done safely, move undamaged containers away from the area around the fire. Dike runoff from fire control for later disposal. Avoid aiming straight or solid streams directly onto the product.

FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2020)

Non-Fire Response

Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:

ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basem*nts or confined areas. A vapor-suppressing foam may be used to reduce vapors.

SMALL SPILL: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Use clean, non-sparking tools to collect absorbed material.

LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2020)

Protective Clothing

Excerpt from NIOSH Pocket Guide for Ethylene dichlorideETHYLENE DICHLORIDE | CAMEO Chemicals (11):

Skin: PREVENT SKIN CONTACT - Wear appropriate personal protective clothing to prevent skin contact.

Eyes: PREVENT EYE CONTACT - Wear appropriate eye protection to prevent eye contact.

Wash skin: WHEN CONTAMINATED - The worker should immediately wash the skin when it becomes contaminated.

Remove: WHEN WET (FLAMMABLE) - Work clothing that becomes wet should be immediately removed due to its flammability hazard (i.e., for liquids with a flash point <100°F).

Change: No recommendation is made specifying the need for the worker to change clothing after the workshift.

Provide:
• EYEWASH - Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed to the substances; this is irrespective of the recommendation involving the wearing of eye protection.
• QUICK DRENCH - Facilities for quickly drenching the body should be provided within the immediate work area for emergency use where there is a possibility of exposure. [Note: It is intended that these facilities provide a sufficient quantity or flow of water to quickly remove the substance from any body areas likely to be exposed. The actual determination of what constitutes an adequate quick drench facility depends on the specific circ*mstances. In certain instances, a deluge shower should be readily available, whereas in others, the availability of water from a sink or hose could be considered adequate.] (NIOSH, 2022)

DuPont Tychem® Suit Fabrics

Fabric legend, testing details, and a caution from DuPont

Tychem® Fabric Legend

QS = Tychem 2000 SFR
QC = Tychem 2000
SL = Tychem 4000
C3 = Tychem 5000
TF = Tychem 6000
TP = Tychem 6000 FR
RC = Tychem RESPONDER® CSM
TK = Tychem 10000
RF = Tychem 10000 FR

Testing Details

The fabric permeation data was generated for DuPont by a third party laboratory. Permeation data for industrial chemicals is obtained per ASTM F739. Normalized breakthrough times (the time at which the permeation rate exceeds 0.1 μg/cm2/min) are reported in minutes. All chemicals have been tested between approximately 20°C and 27°C unless otherwise stated. All chemicals have been tested at a concentration of greater than 95% unless otherwise stated. Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% relative humidity per military standard MIL-STD-282. "Breakthrough time" for chemical warfare agents is defined as the time when the cumulative mass which permeated through the fabric exceeds the limit in MIL-STD-282 [either 1.25 or 4.0 μg/cm2].

A Caution from DuPont

This information is based upon technical data that DuPont believes to be reliable on the date issued. It is subject to revision as additional knowledge and experience are gained. The information reflects laboratory performance of fabrics, not complete garments, under controlled conditions. It is intended for informational use by persons having technical skill for evaluation under their specific end-use conditions, at their own discretion and risk. It is the user's responsibility to determine the level of toxicity and the proper personal protective equipment needed. Anyone intending to use this information should first verify that the garment selected is suitable for the intended use. In many cases, seams and closures have shorter breakthrough times and higher permeation rates than the fabric. If fabric becomes torn,abraded or punctured, or if seams or closures fail, or if attached gloves, visors, etc. are damaged, end user should discontinue use of garment to avoid potential exposure to chemical. Since conditions of use are outside our control, DuPont makes no warranties, express or implied, including, without limitation, no warranties of merchantability or fitness for a particular use and assume no liability in connection with any use of this information. This information is not intended as a license to operate under or a recommendation to infringe any patent, trademark or technical information of DuPont or others covering any material or its use.

Normalized Breakthrough Times (in Minutes)
Chemical CAS Number State QS QC SL C3 TF TP RC TK RF
Dichlorethane, 1.2.- 107-06-2 Liquid imm >480 93 93 >480 >480 >480
Ethylene dichloride 107-06-2 Liquid imm >480 93 93 >480 >480 >480

> indicates greater than.
"imm" indicates immediate; having a normalized breakthrough time of 10 minutes or less.

Special Warning from DuPont: Tychem® and Tyvek® fabrics should not be used around heat, flames, sparks or in potentially flammable or explosive environments. Only...

More Info...

...Tychem® ThermoPro, Tychem® Reflector® and Tychem® TK styles 600T/601T (with aluminized outer suit) garments are designed and tested to help reduce burn injury during escape from a flash fire. Users of Tychem® ThermoPro, Tychem® Reflector® and Tychem® TK styles 600T/601T (with aluminized outer suit) garments should not knowingly enter an explosive environment. Tychem® garments with attached socks must be worn inside protective outer footwear and are not suitable as outer footwear. These attached socks do not have adequate durability or slip resistance to be worn as the outer foot covering.

(DuPont, 2022)

First Aid

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop. IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas.

INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

INGESTION: DO NOT INDUCE VOMITING. Volatile chemicals have a high risk of being aspirated into the victim's lungs during vomiting which increases the medical problems. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. IMMEDIATELY transport the victim to a hospital. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital.

OTHER: Since this chemical is a known or suspected carcinogen you should contact a physician for advice regarding the possible long term health effects and potential recommendation for medical monitoring. Recommendations from the physician will depend upon the specific compound, its chemical, physical and toxicity properties, the exposure level, length of exposure, and the route of exposure. (NTP, 1992)

Physical Properties

What is this information?

The Physical Property fields include properties such as vapor pressure and boiling point, as well as explosive limits and toxic exposure thresholds The information in CAMEO Chemicals comes from a variety of data sources.

Chemical Formula:
  • C2H4Cl2

Flash Point: 56°F(NTP, 1992)

Lower Explosive Limit (LEL): 6.2 %(NTP, 1992)

Upper Explosive Limit (UEL): 15.9 %(NTP, 1992)

Autoignition Temperature: 775°F(USCG, 1999)

Melting Point: -31.5°F(NTP, 1992)

Vapor Pressure: 60 mmHgat 68°F; 100 mmHg at 84.9°F(NTP, 1992)

Vapor Density (Relative to Air): 3.4 (NTP, 1992)

Specific Gravity: 1.253 at 68°F(USCG, 1999)

Boiling Point: 182.3°Fat 760 mmHg(NTP, 1992)

Molecular Weight: 98.96 (NTP, 1992)

Water Solubility: 5 to 10 mg/mLat 66°F(NTP, 1992)

Ionization Energy/Potential:11.05 eV(NIOSH, 2022)

IDLH: 50 ppm; A potential occupational carcinogen.(NIOSH, 2022)

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

Chemical ERPG-1 ERPG-2 ERPG-3
1,2-Dichloroethane (107-06-2) 50 ppm ETHYLENE DICHLORIDE | CAMEO Chemicals (12) 200 ppm 300 ppm

ETHYLENE DICHLORIDE | CAMEO Chemicals (13) indicates that odor should be detectable near ERPG-1.

(AIHA, 2020)

PACs (Protective Action Criteria)

Chemical PAC-1 PAC-2 PAC-3
Ethylene dichloride; (1,2-Dichloroethane) (107-06-2) 50 ppm 200 ppm 300 ppm LEL = 62000 ppm

(DOE, 2018)

Regulatory Information

What is this information?

The Regulatory Information fields include information from the U.S. Environmental Protection Agency's Title III Consolidated List of Lists, the U.S. Cybersecurity and Infrastructure Security Agency's Chemical Facility Anti-Terrorism Standards, and the U.S. Occupational Safety and Health Administration's Process Safety Management of Highly Hazardous Chemicals Standard List (see more about these data sources).

EPA Consolidated List of Lists

Regulatory Name CAS Number/
313 Category Code
EPCRA 302
EHS TPQ
EPCRA 304
EHS RQ
CERCLA RQ EPCRA 313
TRI
RCRA
Code
CAA 112(r)
RMP TQ
1,2-Dichloroethane 107-06-2 100 pounds 313 U077
Ethylene dichloride 107-06-2 100 pounds X U077
  • "X" indicates that this is a second name for an EPCRA section 313 chemical already included on this consolidated list. May also indicate that the same chemical with the same CAS number appears on another list with a different chemical name.

(EPA List of Lists, 2022)

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

Alternate Chemical Names

What is this information?

This section provides a listing of alternate names for this chemical, including trade names and synonyms.

  • ALPHA, BETA-DICHLOROETHANE
  • 1,2-BICHLOROETHANE
  • BORER SOL
  • BROCIDE
  • DCE
  • 1,2-DCE
  • DESTRUXOL BORER-SOL
  • DI-CHLOR-MULSION
  • DICHLOR-MULSION
  • DICHLOREMULSION
  • 1,2-DICHLORETHANE
  • 1, 2-DICHLOROETHANE {ETHYLENE DICHLORIDE}
  • 1,2-DICHLOROETHANE
  • DUTCH LIQUID
  • DUTCH OIL
  • EDC
  • ENT 1,656
  • ETHANE DICHLORIDE
  • ETHYLENE CHLORIDE
  • ETHYLENE DICHLORIDE
  • 1,2-ETHYLENE DICHLORIDE
  • FREON 150
  • GLYCOL DICHLORIDE
  • HCC 150
  • NCI-C00511
  • NU-G00511
  • SYM-DICHLOROETHANE

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Web site owner: Office of Response and RestorationETHYLENE DICHLORIDE | CAMEO Chemicals (15), National Ocean ServiceETHYLENE DICHLORIDE | CAMEO Chemicals (16), National Oceanic and Atmospheric AdministrationETHYLENE DICHLORIDE | CAMEO Chemicals (17). USA.govETHYLENE DICHLORIDE | CAMEO Chemicals (18).

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ETHYLENE DICHLORIDE | CAMEO Chemicals (2024)

FAQs

What products contain ethylene dichloride? ›

Ethylene dichloride (EDC) is used primarily for the production of vinyl chloride monomer (VCM), which is used mainly in the polymerization manufacture of polyvinyl chloride (PVC). PVC is commonly used in pipes, fittings, profiles, tubes, windows, doors, sidings, wire, cable, film, sheet and flooring.

Is ethylene dichloride harmful to humans? ›

Acute exposure to ethylene dichloride seemed to most frequently affect the cardiovascular system as evidenced by extreme lowering of blood pressure, and cardiac impairment. Other toxic effects include pulmonary edema, fatty degeneration of the liver and kidney (renal tubules) and degeneration of the adrenal cortex.

What is ethylene dichloride used for? ›

The chemical compound 1,2-dichloroethane, commonly known as ethylene dichloride (EDC), is a chlorinated hydrocarbon, mainly used to produce vinyl chloride monomer (VCM, chloroethene), the major precursor for PVC production.

Does ethylene dichloride mix with water? ›

ethylene chloride (C2H4Cl2), also called ethylene dichloride or 1,2-dichloroethane, a colourless, toxic, volatile liquid having an odour resembling that of chloroform. It is denser than water, and it is practically insoluble in water.

Where is ethylene commonly found? ›

Ethylene is a natural product emitted by fruits, flowers, leaves, roots and tubers (Altshuller, 1983). The rate of release varies during the life cycle of the plant.

What is the most common source of ethylene? ›

Natural sources of ethylene include both natural gas and petroleum; it is also a naturally occurring hormone in plants, in which it inhibits growth and promotes leaf fall, and in fruits, in which it promotes ripening.

What is another name for ethylene dichloride? ›

1,2-dichloroethane is a highly flammable colourless liquid with a chloroform-like odour. Other common names for 1,2-dichloroethane are dichloroethane, ethylene chloride, ethylene dichloride, EDC and Dutch liquid.

What are the symptoms of exposure to ethylene chloride? ›

Inhalation of concentrated ethylene dichloride vapor can induce effects on the human nervous system, liver, and kidneys, as well as respiratory distress, cardiac arrhythmia, nausea, and vomiting. Chronic (long-term) inhalation exposure to ethylene dichloride produced effects on the liver and kidneys in animals.

What are the two most severe hazards of ethylene? ›

* Exposure to Ethylene can cause headache, dizziness, fatigue, lightheadedness, confusion and unconsciousness. * Ethylene is a HIGHLY FLAMMABLE and REACTIVE chemical and a DANGEROUS FIRE and EXPLOSION HAZARD.

What does ethylene dichloride look like? ›

Ethylene dichloride appears as a clear colorless liquid with a chloroform-like odor. Flash point 56 °F.

What can ethylene oxide do to you? ›

Acute exposures to EtO gas may result in respiratory irritation and lung injury, headache, nausea, vomiting, diarrhea, shortness of breath, and cyanosis. Chronic exposure has been associated with the occurrence of cancer, reproductive effects, mutagenic changes, neurotoxicity, and sensitization.

Why is ethylene toxic? ›

Ethylene glycol breaks down into toxic compounds in the body. Ethylene glycol and its toxic byproducts first affect the central nervous system (CNS), then the heart, and finally the kidneys. Ingesting enough can cause death.

Where does ethylene dichloride come from? ›

Ethylene dichloride (EDC) Is produced from ethylene and chlorine by direct chlorination, and from ethylene and hydrogen chloride (HCl) by oxychlorination. At most production facilities, these processes are used together in what is known as the balanced process.

What household products is ethylene in? ›

Ethylene oxide is used to make a variety of products found all around your house – from shampoos to disinfectants to laundry detergent. It is also a necessary ingredient for some highly durable fabrics and textiles used in clothing, carpet, upholstery, and pillows.

What products are made from ethylene? ›

Ethylene is one of the most important petrochemical intermediates and is a feedstock for many various products. End products made with ethylene include food packaging, film, toys, food containers, bottles, pipes, antifreeze, carpets, insulation, housewares, etc.

What products use ethylene? ›

Polymers of ethylene are used to manufacture fibers, bins, pails, crates, bottles, piping, food packaging films, trash liners, bags, wire and cable sheathing, insulation, surface coatings for paper and cardboard, and wide variety of other products including tile and flooring for building and construction.

What everyday products contain ethylene glycol? ›

DESCRIPTION: Ethylene glycol is a useful industrial compound found in many consumer products. Examples include antifreeze, hydraulic brake fluids, some stamp pad inks, ballpoint pens, solvents, paints, plastics, films, and cosmetics. It can also be a pharmaceutical vehicle.

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